No. Comio S1 does not the face recognition ability.
No. Comio S1 does not have dual rear camera. It has single lens camera with 13MP resolution.
Yes, Comio S1 does have support for Jio VoLTE also. You will be able to use Airtel VoLTE as well.
Comio S1 does have a very decent battery back up. It has 2700 mAh Li-Polymer non-removable battery which offers almost 15 hours of talk time and up to 143 hours of stand by period.